Organic Seminar - Ana Bahamonde

The Organic Seminar Series presents: Ana Bahamonde
University of California, Riverside
Host: Kami Hull
Title: Beginning to understand light-mediated Ni catalysis using physical organic techniques and data science
Refreshments served at 3:15pm

Location: WEL 2.122

The Bahamonde group harnesses the distinct one-electron chemistry and photochemical reactivity of Ni complexes to generate and trap C-centered radicals enantioselectively and promote C−N reductive eliminations at room temperature. Our excitement for studying these systems stems from the fact that these two apparently unrelated processes are facilitated under almost identical conditions, but to date the ligand features, photocatalyst properties, and subtle reaction condition variations that favor one pathway over the other are not yet understood. Additionally, to expedite reaction optimization, the group develops multivariate linear regression models correlating observed enantioselectivity to computed molecular descriptors.